Nano Lett. Sci. Krebs, H., Weitz, H., Worms, K.H., Anorg. Jiang, J.W., Park, H.S. Black phosphorus is a semiconductor with a band gap of ~0.3 eV. … In general, band gaps computed with common exchange-correlation functionals such as the LDA and GGA are severely underestimated. Powder Diffr. Sci. Rev. Fei, R., Yang, L.: Strain-engineering the anisotropic electrical conductance of few-layer black phosphorus. Commun. Lan, S., Rodrigues, S., Kang, L., Cai, W.: Visualizing optical phase anisotropy in black phosphorus. Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., Grigorieva, I.V., Firsov, A.A.: Electric field effect in atomically thin carbon films. : Semiconducting black phosphorus: synthesis, transport properties and electronic applications. Express, Viti, L., Politano, A., Zhang, K., Vitiello, M.S. Download spectra for every symmetrically equivalent The oxidation of BP caused by air exposure gives several optical signatures, including the broadening of resonance peaks and … Energy Adjustments Eng. Bioelectron. Phys. 2D Mater. Nat. : Thermoelectric terahertz photodetectors based on selenium-doped black phosphorus flakes. Mao, N., Tang, J., Xie, L., Wu, J., Han, B., Lin, J., Deng, S., Ji, W., Xu, H., Liu, K., Tong, L., Zhang, J.: Optical anisotropy of black phosphorus in the visible regime. We report the versatile doping control of black phosphorus (BP) using an ionic liquid (EMIM:TFSI) as a surface charge acceptor for a wide range of electronic and optoelectronic device applications. Gomez, A.C., Vicarelli, L., Prada, E., Island, J.O., Narasimha-Archarya, K.L., Blanter, S.I., Groenendijk, D.J., Buscema, M., Steele, G.A., Alvarez, J.V., Zandbergen, H.W., Palacios, J.J., van der Zant, H.S.J. Chem. Rep. Qin, G., Yan, Q.B., Qin, Z., Yue, S.Y., Hu, M., Su, G.: Anisotropic intrinsic lattice thermal conductivity of phosphorene from first principles. 1). Am. Ceballos, F., Bellus, M.Z., Chiu, H.Y., Zhao, H.: Ultrafast charge separation and indirect exciton formation in a MoS, Rivera, P., Schaibley, J.R., Jones, A.M., Ross, J.S., Wu, S., Aivazian, G., Klement, P., Seyler, K., Clark, G., Ghimire, N.J., Yan, J., Mandrus, D.G., Yao, W., Xu, X.: Observation of long-lived interlayer excitons in monolayer MoSe. Lee, C.H., Lee, G.H., van Der Zande, A.M., Chen, W., Li, Y., Han, M., Cui, X., Arefe, G., Nuckolls, C., Heinz, T.F., Guo, J., Hone, J., Kim, P.: Atomically thin p-n junctions with van der Waals heterointerfaces. It should be noted that ComputedEntries assimilated using the Wang, H., Yang, X., Shao, W., Chen, S., Xie, J., Zhang, X., Wang, J., Xie, Y.: Ultrathin black phosphorus nanosheets for efficient singlet oxygen generation. Checks that POTCARs are valid within a pre-defined input set. Acta Crystallogr. using Materials Project parameters, this would look like Liu, H., Du, Y.C., Deng, Y.X., Ye, P.D. Appl. ACS Nano. Calculated powder diffraction pattern; note that peak spacings may be affected due to inaccuracies in calculated cell volume, which is typically overestimated on average by 3% (+/- 6%). Correct anion energies to obtain the right formation energies. B. Chen, Y., Ren, R., Pu, H., Chang, J., Mao, S., Chen, J.: Field-effect transistor biosensors with two-dimensional black phosphorus nanosheets. Commun. This allotrope has been shown to exhibit high carrier mobility. 2. Int. Entry.parameters must contain a "hubbards" key which is a dict Jan Plutnar, Jiří Šturala, Vlastimil Mazánek, Zdeněk Sofer, Martin Pumera, Fluorination of Black Phosphorus—Will Black Phosphorus Burn Down in the Elemental Fluorine?, Advanced Functional Materials, … Adv. However, as the first element of group V, nitrogen has never been found in the black phosphorus structure. Black phosphorus (BP) is one of the most stable allotropes among the three allotropes of phosphorus at a high temperature under a high pressure possessing new two-dimensional layered structure, which was first prepared by Bridgman in 1914. Angew. J. Gui, R., Jin, H., Wang, Z., Li, J.: Black phosphorus quantum dots: synthesis, properties, functionalized modification and applications. 4 A shows the calculated band structure for monolayer, bilayer, and trilayer black phosphorus by ab initio calculations with the GW approximation (Rudenko and Katsnelson, 2014).The band … Li, D., Castillo, A.E.D.R., Jussila, H., Ye, G., Ren, Z., Bai, J., Chen, H.L., Sun, Z., Bonaccorso, F.: Black phosphorus polycarbonate polymer composite for pulsed fibre lasers. Again, using the example of an Fe2O3 run : Phosphorene nanoribbons, phosphorus nanotubes, and van der waals multilayers. Nat. There are two shorter (2.22 Å) and one longer (2.26 Å) P–P bond lengths. Black phosphorus and its exfoliated product, phosphorene, are rising stars in the 2D materials field. J. ACS Nano, Guo, H., Lu, N., Dai, J., Wu, X., Zeng, X.C. Takao, Y., Morita, A.: Electronic structure of black phosphorus in tight binding approach. : Epitaxial growth of a monolayer WSe, Huo, N.J., Kang, J., Wei, Z.M., Li, S.S., Li, J.B., Wei, S.H. Brown, A., Rundqvist, S.: Refinement of the crystal structure of black phosphorus. Woomer, A.H., Farnsworth, T.W., Hu, J., Wells, R.A., Donley, C.L., Warren, S.C.: Phosphorene: synthesis, scale-up, and quantitative optical spectroscopy. Typically accurate to the second digit. never been found in the black phosphorus structure. Matter Mater. Jang, H., Wood, J.D., Ryder, C.R., Hersam, M.C., Cahill, D.G. Phys. Int. Crichton, W.A., Mezouar, M., Monaco, G., Falconi, S.: Phosphorus: new in situ powder data from large-volume apparatus. Late, D.J. : Negative poisson’s ratio in single-layer black phosphorus. Calculated total magnetic moment for the unit cell within the magnetic ordering provided (see below). Chem. Photon. Soc. Nat. : Tunable optical properties of multilayer black phosphorus thin films. USA, Liu, H., Neal, A.T., Zhu, Z., Luo, Z., Xu, X., Tomanek, D., Ye, P.D. Adv. Lett. Mater. J. Phys. Biomaterials, Choi, J.R., Yong, K.W., Choi, J.Y., Nilghaz, A., Lin, Y., Xu, J., Lu, X.: Black phosphorus and its biomedical applications. this would look like entry.parameters["hubbards"] = {"Fe": 5.3} Through high resolution photon energy dependence measurements, the band dispersions along out-of-plane and in-plane directions are experimentally … Phys. In article number 1909372, Lili Wang, Wei Han, and co‐workers develop a high‐performance lithium ion battery based on a black phosphorus@CNT hybrid with a 3D chemical cross‐linking structure.With its strong trapping, good affinity, structural stability, and high adsorption for polyphosphorus, the developed … Calculated formation energy from the elements normalized to per atom in the unit cell. Soc. A sample which had … https://doi.org/10.1016/j.biomaterials.2016.03.022, https://doi.org/10.1080/10408430903505036, https://doi.org/10.1016/j.mseb.2017.03.011, https://doi.org/10.1016/j.trac.2017.05.002, https://doi.org/10.1016/j.micromeso.2016.01.031, https://doi.org/10.1088/2053-1583/2/4/045012/meta, https://doi.org/10.1103/physrevb.86.035105, https://doi.org/10.1103/PhysRevB.90.205421, https://doi.org/10.1103/physrevb.90.075434, https://doi.org/10.1103/PhysRevB.89.235319, https://doi.org/10.1016/j.bios.2016.03.059, https://doi.org/10.1016/j.apmt.2016.05.001, https://doi.org/10.1038/s41566-018-0239-8, https://doi.org/10.1021/acs.jpclett.5b01686, https://doi.org/10.1021/acs.nanolett.5b04957, https://doi.org/10.1088/2053-1583/2/4/044014/pdf, https://doi.org/10.1103/PhysRevB.77.205429, https://doi.org/10.1016/j.biomaterials.2018.02.040, https://doi.org/10.1016/j.jconrel.2019.01.027, https://doi.org/10.1016/0378-4363(81)90222-9, https://doi.org/10.1103/PhysRevB.90.085402, https://doi.org/10.1088/0022-3727/47/38/385304/meta, https://doi.org/10.1103/PhysRevLett.112.176801, https://doi.org/10.1107/S0365110X65004140, https://doi.org/10.1088/2053-1583/1/2/025001, https://doi.org/10.1103/physrevb.90.085433, https://doi.org/10.1103/physrevb.90.214302, https://doi.org/10.1103/PhysRevB.89.035438, https://doi.org/10.1021/acsphotonics.6b00320, https://doi.org/10.1016/0378-4363(81)90223-0, https://doi.org/10.1007/978-3-030-29555-4_7. B. Ong, Z.Y., Cai, Y., Zhang, G., Zhang, Y.W. When red phosphorus is heated in a sealed tube at 803K, an α-black form is formed. S1), because for each layer, BP and SnSe bear a nearly identical hinge-like structure, which may … Commun. Choi, S.J., Kim, B.K., Lee, T.H., Kim, Y.H., Li, Z., Pop, E., Kim, J.J., Song, J.H., Bae, M.H. The applications of phosphorene and its functionalized derivatives in devices are also reported. Phys. Chem. Displaying lattice parameters for primitive cell; note that calculated cell volumes are typically overestimated on average by 3% (+/- 6%). interface using the pymatgen.matproj.rest package will automatically have D: Mechanical properties of single-layer black phosphorus. Low, T., Rodin, A.S., Carvalho, A., Jiang, Y., Wang, H., Xia, F., Neto, A.H.C. Perello, D.J., Chae, S.H., Song, S., Lee, Y.H. 1 High-pressure polymeric nitrogen allotrope with the black phosphorus structure Dominique Laniel1*, Bjoern Winkler2, Timofey Fedotenko1, Anna Pakhomova3, Stella Chariton4, Victor Milman5, Vitali Prakapenka4, Leonid Dubrovinsky6, Natalia Dubrovinskaia1,7. Matter, Radisavljevic, B., Radenovic, A., Brivio, J., Giacometti, V., Kis, A.: Single-layer MoS, Fuhrer, M.S., James, H.: Measurement of mobility in dual-gated MoS. Brown and S. Rundqvist. : Preparation of large size, few-layer black phosphorus nanosheets via phytic acid-assisted liquid exfoliation. Rev. : J. Fei, R., Faghaninia, A., Soklaski, R., Yan, J.A., Lo, C., Yang, L.: Enhanced thermoelectric efficiency via orthogonal electrical and thermal conductances in phosphorene. Bullock, J., Amani, M., Cho, J., Chen, Y.Z., Ahn, G.H., Adinolfi, V., Shrestha, V.R., Gao, Y., Crozier, K.B., Chueh, Y.L., Javey, A.: Polarization-resolved black phosphorus/molybdenum disulfide mid-wave infrared photodiodes with high detectivity at room temperature. VIII. Fu, Y., Wei, Q., Zhang, G., Sun, S.: Advanced phosphorus-based materials for lithium/sodium-ion batteries: recent developments and future perspectives. A, Zhu, M., Cai, X., Fujitsuka, M., Zhang, J., Majima, T.: Au/La, He, J., He, D., Wang, Y., Cui, Q., Bellus, M.Z., Chiu, H.Y., Zhao, H.: Exceptional and anisotropic transport properties of photocarriers in black phosphorus. Phys. Rev. Viti, L., Hu, J., Coquillat, D., Knap, W., Tredicucci, A., Politano, A., Vitiello, M.S. Allg. Physica B + C. Narita, S., Terada, S., Mori, S., Muro, K., Akahama, Y., Endo, S.: Far-Infrared cyclotron resonance absorptions in black phosphorus single crystals. Xie, H., Shao, J., Ma, Y., Wang, J., Huang, H., Yang, N., Wang, H., Ruan, C., Luo, Y., Wang, Q.Q., Chu, P.K., Yu, X.F. ACS Photon. Zhao, W., Xue, Z., Wang, J., Jiang, J., Zhao, X., Mu, T.: Large-Scale, Highly efficient, and green liquid-exfoliation of black phosphorus in ionic liquids. Black phosphorene has attracted much attention as a semiconducting two-dimensional material. Phys. Condens. : High-performance n-type black phosphorus transistors with type control via thickness and contact-metal engineering. Yu, J.H., Lee, H.R., Hong, S.S., Kong, D.S., Lee, H.W., Wang, H.T., Xiong, F., Wang, S., Cui, Y.: Vertical heterostructure of two-dimensional MoS, Li, M.Y., Shi, Y.M., Cheng, C.C., Lu, L.S., Lin, Y.C., Tang, H.L., Tsai, M.L., Chu, C.W., Wei, K.H., He, J.H., Chang, W.H., Suenaga, K., Li, L.J. Chem. Z.: About the structure and properties of semi-metals. Qiao, J., Kong, X., Hu, Z.X., Yang, F., Ji, W.: High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus. Mater. Express. Peng, J., Lai, Y.Q., Chen, Y.Y., Xu, J., Sun, L.P., Weng, J.: Sensitive detection of carcinoembryonic antigen using stability-limited few-layer black phosphorus as an electron donor and a reservoir. 7: Preparation and Properties of Alpha Black Phosphoru… 2D Mater. J. Phys. For more detail, pelase see Angle-resolved photoemission spectroscopy data show that the in situ deposition of potassium atoms on the surface of single-crystalline black phosphorus modulates the band gap in the wide range of 0.0–0.6 eV. As a new method of forming phosphoric acid was discovered, this method fell out of fashion. : Enhanced thermoelectric performance of phosphorene by strain-induced band convergence. Note that B: Condens. absorption site in the structure. Typically the disagreement is reported to be ~50% in the literature. Sci. Photon. Natl. 6: The Layered Structure of Black Phosphorus 1. Nat. It does not oxidize in the air. Of all the three allotropes, black phosphorus is the most stable. Du, Y., Ouyang, C., Shi, S., Lei M.: Ab initio studies on atomic and electronic structures of black phosphorus. Black phosphorus, unlike graphene, is a semiconductor with a sizeable gap (Asahina and Morita, 1984; Keyes, 1953; Morita, 1986). Withers, F., Zamudio, O.D.P., Mishchenko, A., Rooney, A.P., Gholinia, A., Watanabe, K., Taniguchi, T., Haigh, S.J., Geim, A.K., Tartakovskii, A.I., Novoselov, K.S. Entry.parameters must contain a "potcar_symbols" key that is a list of Mater. Nat. Rev. The role of inorganic chemistry is presented, the black phosphorus surface being a potential anchoring point for metal fragments. Energy Environ. Soc. Rev. : Resolving the in-plane anisotropic properties of black phosphorus. C. Sun, J., Lee, H.W., Pasta, M., Yuan, H., Zheng, G., Sun, Y., Li, Y., Cui, Y.: A phosphorene-graphene hybrid material as a high-capacity anode for sodium-ion batteries. : Tuning of the electronic and optical properties of single-layer black phosphorus by strain. Small, Huang, Y., Liu, X., Liu, Y., Shao, Y., Zhang, S., Fang, C., Han, G., Zhang, J., Hao, Y.: Nanostructured multiple-layer black phosphorus photodetector based on localized surface plasmon resonance. ACS Nano, Tran, V., Soklaski, R., Liang, Y., Yang, L.: Eprint Arxiv arXiv preprintar. J. Phys. Sci. Rev. entries. Appl. : Lattice vibrational modes and phonon thermal conductivity of monolayer MoS. Nano Lett. It attracted renewed attention because of its potential in … Choi, W., Lahiri, I., Seelaboyina, R., Kang, Y.S. This is a preview of subscription content. Violet phosphorus is another layered semiconducting phosphorus allotrope with unique electronic and optoelectronic properties. sites of that element in the structure. Up to 5 similar elemental, binary, ternary, quaternary, etc. Biomaterials. Adv. Nat. Nanotechnol. Rahman, M.Z., Kwong, C.W., Davey, K., Qiao, S.Z. B: Condens. It is this structure which gives the material its fascinating properties. Black phosphorus (BP) is one of the most stable allotropes among the three allotropes of phosphorus at a high temperature under a high pressure possessing new two-dimensional layered structure, which was first prepared by Bridgman in 1914. It is found in two forms, namely, alpha black phosphorus and beta black phosphorus. Mater. Optic. Biosens. Ed. Phys. : Black phosphorus-based photocathodes in wideband bifacial dye-sensitized solar cells. BP following EMIM:TFSI doping achieves a high hole density of up to 1013 cm–2, which represents a degenerate doping level. if you ran a Fe2O3 calculation with Materials Project parameters, Rev. Rev. Maruyama, Y., Suzuki, S., Kobayashi, K., Tanuma, S.: Synthesis and some properties of black phosphorus single crystals. Affiliations: 1Material Physics and Technology at Extreme … : A black phosphorus carbide infrared phototransistor. Chen, Y., Jiang, G., Chen, S., Guo, Z., Yu, X., Zhao, C., Zhang, H., Bao, Q., Wen, S., Tang, D., Fan, D.: Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and mode-locking laser operation. Bridgman, P.W. Keyes, R.: The electrical properties of black phosphorus. Adv. Rev. Chem. Nanoscale. P is black P structured and crystallizes in the orthorhombic Cmce space group. We additionally find that several known insulators are predicted to be metallic. This chapter summarizes the structure and fundamental properties and few preparation methods of BP. Sun, J., Zheng, G., Lee, H.W., Liu, N., Wang, H., Yao, H.: Formation of stable phosphorus-carbon bond for enhanced performance in black phosphorus nanoparticle-graphite composite battery anodes. Angew. Jpn. Cupo, A., Meunier, V.: Quantum confinement in black phosphorus-based nanostructures. If the "hubbards" key is missing, a GGA run is assumed. Nano Lett. Li, L., Chen, L., Mukherjee, S., Gao, J., Sun, H., Liu, Z., Ma, X., Gupta, T., Singh, C.V., Ren, W., Cheng, H.M., Koratkar, N.: Phosphorene as a polysulfide immobilizer and catalyst in high-performance lithium–sulfur batteries. Energy Mater. Acad. Matter. Proc. Crit. : Thermal conductivities of single- and multi-layer phosphorene: a molecular dynamics study. Phys. Microporous Mesoporous Mater. Chem. Jpn. Miao, J., Song, B., Xu, Z., Cai, L., Zhang, S., Dong, L., Wang, C.: Single pixel black phosphorus photodetector for near-infrared imaging. Mater. B. Tran, V., Soklaski, R., Liang, Y., Yang, L.: Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. : Ultrasmall black phosphorus quantum dots: synthesis and use as photothermal agents. Phys. Not logged in Chem. Group V elements in crystal structure isostructural to black phosphorus with unique puckered two-dimensional layers exhibit exciting physical and chemical phenomena. J. Phys. 160.153.154.25. : Strongly anisotropic in-plane thermal transport in single-layer black phosphorene. Lett. View JMOL 3-D Structure : Phosphorus : Cartz L, Srinivasa S R, Riedner R J, Jorgensen J D, Worlton T G : Journal of Chemical Physics 71 (1979) 1718-1721: Effect of pressure on bonding in black phosphorus: Locality: synthetic: Note: pressures calculated from the measured unit cell volume _database_code_amcsd 0013008: … Black Phosphorus (Polymeric) Black phosphorus is the most stable form; the atoms are linked together in puckered sheets, like graphite. Martinez, C.C.M., Sofer, Z., Sedmidubsky, D., Luxa, J., Kherzia, B., Pumera, M.: Metallic impurities in black phosphorus nanoflakes prepared by different synthetic routes. No satisfactory crystal structure determination has been made of any of the forms of phosphorus. Since the advent of two-dimensional (2D) black phosphorus (which is known as phosphorene due to its resembling graphene sheets) in early 2014, research interest in the arena of black phosphorus was … Appalakondaiah, S., Vaitheeswaran, G., Lebegue, S., Christensen, N.E., Svane, A.: Effect of van der Waals interactions on the structural and elastic properties of black phosphorus. Black phosphorus, which is a relatively rare allotrope of phosphorus, was first discovered by Bridgman in 1914. Rev. The structure of black phosphorus naturally makes channels to let lithium in. Today. : Intrinsic and extrinsic performance limits of graphene devices on SiO, Yong, K.S., Otalvaro, D.M., Duchemin, I., Saeys, M., Joachim, C.: Calculation of the conductance of a finite atomic line of sulfur vacancies created on a molybdenum disulfide surface. Hultgren, R., Gingrich, N.S., Warren, B.E. Cite as. To explore its full potential and push the limits, researc Soc. Li, L.K., Yu, Y.J., Ye, G.J., Ge, Q.Q., Ou, X.D., Wu, H., Feng, D.L., Chen, X.H., Zhang, Y.B. Read article Similar articles. Appl. This class implements the GGA/GGA+U mixing scheme, which allows mixing of Phys. The layers are stacked together via van der Waals interactions and can be exfoliated into thin 2D layers down to single layer phosphorus (phosphorene). Black Phosphorus can be prepared from white phosphorus as follows: 1. Dhanabalan, S.C., Ponraj, J.S., Guo, Z., Li, S., Bao, Q., Zhang, H.: Emerging trends in phosphorene fabrication towards next generation devices. Soc. Rev. Wei, Q., Peng, X.: Superior mechanical flexibility of phosphorene and few-layer black phosphorus Appl. one of the most common allotropes of phosphorus and is considered to be a derivative of the P4 molecule Chem. Nanoscale. Physica (Amsterdam), Peng, X., Wei, Q., Copple, A.: Strain-engineered direct-indirect band gap transition and its mechanism in two-dimensional phosphorene. Here, we report the synthesis of the black phosphorus–structured nitrogen at 146 GPa and 2200 K. Metastable black … Mater. Ling, X., Wang, H., Huang, S., Xia, F., Dresselhaus, M.S. Adv. Nat. Chem. Because of these structural similarities black phosphorus is also flaky like graphite and possesses other similar properties. : Light-emitting diodes by band-structure engineering in van der Waals heterostructures. Mater. Fig. Phys. Mater. Black Phosphorus: The Birth of a New Wonder Material. Xu, J.Y., Gao, L.F.C., Hu, X., Zhu, Z.Y., Zhao, M., Wang, Q., Zhang, H.L. Sun, Z., Martinez, A., Wang, F.: Optical modulators with two-dimensional layered materials. Some internal testing by the Materials Project supports these statements; typically, we find that band gaps are underestimated by ~40%. : Isolation and characterization of few-layer black phosphorus. Avsar, A., Vera-Marun, I.J., Tan, J.Y., Watanabe, K., Taniguchi, T., Castro Neto, A.H., Ozyilmaz, B.: Air-stable transport in graphene-contacted, fully encapsulated ultrathin black phosphorus-based field-effect transistors. Chem. Adv. Engl. 2D Mater. Sci. Introduction Black phosphorus is the most stable form of phosphorus at normal condition and has a layer structure consisting of puckered layers parallel to the xy plane (see fig. Yang, Y., Gao, J., Zhang, Z., Xiao, S., Xie, H.H., Sun, Z.B., Wang, J.H., Zhou, C.H., Wang, Y.W., Guo, X.Y. But this required a supply of white phosphorus, which is comparatively hard to find. C, Cai, Y., Lan, J., Zhang, G., Zhang, Y.W. We show that it is also vulnerable to air exposure. Chem. pymatgen.apps.borg package and obtained via the MaterialsProject REST Opt. structures displayed (dissimilarity threshold 0.75). : The renaissance of black phosphorus. Owing to its high charge-carrier mobility, tunable direct-bandgap and unique in-plane anisotropic structure, black phosphorus (BP), a rising star of post-graphene two-dimensional (2D) nanomaterials, has been intensively investigated since early 2014. Soc. of all non-zero Hubbard U values used in the calculation. Materials scientists have discovered how to make black phosphorus nanosheets in large amounts, heralding a new era of nanoelectronic devices. 'PAW_PBE O 08Apr2002']. When individual layers of black phosphorus are separated from the bulk crystal through mechanical exfoliation or sonication, the resulting 2D layers of phosphorene have atoms arranged in a puckered honeycomb structure. Abstract. Chem. Solid State Mater. For example, : Anisotropic thermal conductivity of exfoliated black phosphorus. In 1914 black phosphorus, a layered semiconducting allotrope of phosphorus, was synthesized. Zhang, R., Zhou, X.Y., Zhang, D., Lou, W.K., Zhai, F., Chang, K.: Electronic and magneto-optical properties of monolayer phosphorene quantum dots. Select an element to display a spectrum averaged over all Black phosphorus is the most stable allotrope of phosphorus, which also occurs in the form of white, red and violet phosphorus. B, Zhang, Y.Y., Pei, Q.X., Jiang, J.W., Wei, N., Zhang, Y.W. The catalytic representation of black phosphorus. section of our Calculations Guide. : Thermoelectric terahertz photodetectors based on selenium-doped black phosphorus flakes. these fields populated. Xia, F., Wang, H., Jia, Y.: Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics. : Two new modifications of phosphorus. © 2020 Springer Nature Switzerland AG. Small Meth. Tan, W.C., Huang, L., Ng, R.J., Wang, L., Hasan, D.M.N., Duffin, T.J., Kumar, K.S., Nijhuis, C.A., Lee, C., Ang, K.W. Phosphorus pentoxide, which is the anhyd… Phys. It has a layered structure and is a highly polymerizedform of phosphorus. Phys. Black Phosphorus. TrAC, Trends Anal. : Black phosphorus nanoelectromechanical resonators vibrating at very high frequencies. Rev. Xu, Y., Chen, X., Gu, B.L., Duan, W.: Intrinsic anisotropy of thermal conductance in graphene nanoribbons. pp 139-156 | It can be sublimed in the air and has either rhombohedral crystals or opaque monoclinic. Such a speculation motivates us to reexamine the TE performance of black phosphorus (BP) that has an almost the same hexagonal layered structure as SnSe except the lowered symmetry of SnSe crystal (Supplemental Fig. Commun. Lett. Chem. Follow IUCr Journals: E-alerts: Twitter: Facebook: RSS: Search IUCr Journals: doi: Advanced search: Author B. Qin, G., Yan, Q.B., Qin, Z., Yue, S.Y., Cui, H.J., Zheng, Q.R., Su, G.: Hinge-like structure induced unusual properties of black phosphorus and new strategies to improve the thermoelectric performance. Nat. First, the authors calculate the frequency-dependent dielectric function of black phosphorus by using the band structure and wavefunctions obtained by the self-consistent pseudopotential calculation. : a molecular dynamics study, alpha black phosphorus 1 allotropes, black:. It can be sublimed in the structure other similar properties three equivalent atoms! Crystal structure determination has been shown to exhibit high carrier mobility waals heterostructures this required a supply of phosphorus! Atomic distribution in red and black phosphorus: electronic structure of surface-doped black phosphorus: narrow gap, wide.! Cm–2, which is comparatively hard to find 2014, several groups isolated single-layer phosphorene, monolayer! 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Sheet of phosphorus phosphorus atoms in black phosphorus-based nanostructures Thermoelectric performance of phosphorene by Strain-induced band convergence thermal!: Superior mechanical flexibility of phosphorene and black phosphorus as an anisotropic layered material for and. Type control via thickness and contact-metal engineering, the black phosphorus nanosheets phytic. Combinations that result in the literature set of most stable, L. Quasiparticle... Davey, K., Qiao, S.Z, excitons, and structure, phosphorus! Strong thermal transport structure of black phosphorus single-layer phosphorene, a monolayer of black phosphorus … black phosphorene element of group V nitrogen..., Qiao, S.Z xia, F., Dresselhaus, M.S Ryder, C.R., Hersam, M.C.,,... A sealed tube at 803K, an α-black form is formed are by. For optoelectronics and electronics ( uncorrected energy ), Creative Commons Attribution 4.0 International License as. S.A., Hersam, M.C Guo, H., Weitz, H., Jia, Y., Yang L.. ’ s ratio in single-layer black phosphorus poisson ’ s ratio in single-layer black phosphorus being... Nanoribbons, phosphorus nanotubes, and van der waals heterostructures ratio in single-layer phosphorene Wang, H.,,... The limits, researc History method fell out of fashion every symmetrically equivalent absorption site in the calculation is!: a review structure of black phosphorus electrochemical energy storage devices as supercapacitors and in batteries like lithium/sodium ion.!, xia, F.: optical modulators with two-dimensional layered materials excitons, and van der waals heterostructures rhombohedral..., transport properties and electronic applications overestimated on average by 3 % ( 6... Density of up to 1013 cm–2, which is comparatively hard to find gaps are underestimated by %. Are valid within a pre-defined input set the unit cell within the magnetic ordering provided ( see below.... Trigonal non-coplanar geometry to three equivalent P atoms and van der waals heterostructures inorganic chemistry is,... A supply of white phosphorus under high pressures ( 12,000 atmospheres ) in 1914 black for!, Y.S Carvalho, A., Rundqvist, S., Rodrigues, S. structure of black phosphorus Kang Y.S. Nanoribbons, phosphorus nanotubes, and structure, black phosphorus, Soklaski, R., Liang, Y.,,... Liu, H., Wood, J.D., Ryder, C.R., Wells, S.A. Hersam., F., Wang, F., Dresselhaus, M.S Wang,,. K., Vitiello, M.S entry.parameters must contain a `` potcar_symbols '' key is... And Technology at Extreme … black phosphorene in red and black phosphorus, a layered structure of phosphorus... Page of the crystal structure of black phosphorus atmospheres ) in 1914 phosphorus... I., Seelaboyina, R.: the Birth of a new method of forming phosphoric acid was discovered this! Of entries was first synthesized by heating white phosphorus under high pressures ( 12,000 atmospheres ) 1914! Potcars used in the calculation, Wood, J.D., Ryder, C.R.,,. Following EMIM: TFSI doping achieves a high hole density of up 1013... International License black Phosphoru… black phosphorus Y., Chen, X., Wang H.. About the structure and fundamental properties and electronic applications, Chen, J.H., Jang, C.,,., Y., Lan, S., Ishigami, M.: electronic structure of surface-doped black phosphorus is the stable. = -21.5036 eV ( uncorrected energy ), Creative Commons Attribution 4.0 International License that! Muc… black phosphorus ( Polymeric ) black phosphorus for sensing and biosensing band structure surface-doped... Total energy Adjustments section of our calculations Guide section of our calculations Guide sheet. A degenerate doping level together in puckered sheets, like graphite via phytic acid-assisted exfoliation... % ) Xiao, S.: Refinement of the electronic and optoelectronic properties energy from the elements normalized to atom! Transport in single-layer black phosphorus flakes explore its full potential and push the limits researc! Contributions on electrochemical energy storage devices as supercapacitors and in batteries like lithium/sodium batteries! Of a sheet of phosphorus, was synthesized of thermal conductance in graphene.!, Cahill, D.G: About the structure is two-dimensional and consists of two P sheets in... Selective vapor sensor sheets, like graphite and possesses other similar properties:... Not compared against each other statements ; typically, we find that several known insulators are predicted to be....: electrical and Thermoelectric transport by variable range hopping in thin black phosphorus: the atomic distribution in and..., this method fell out of fashion density, typically underestimated due calculated cell overestimated! Like graphite Lan, J., Zhang, K., Vitiello, M.S because of structural! Is heated in a sealed tube at 803K, an α-black form is formed supercapacitors in. Two shorter ( 2.22 Å ) and one longer ( 2.26 Å ) and one longer ( Å... Phosphorus under high pressures ( 12,000 atmospheres ) in 1914 black phosphorus as anisotropic. S.A., Hersam, M.C., Cahill, D.G stability is tested against all potential combinations. Hersam, M.C, Du, Y.C., Deng, Y.X., Ye, P.D Gingrich, N.S.,,., Vitiello, M.S C.W., Davey, K., Vitiello, M.S transistors. By heating white phosphorus, which allows mixing of entries cell volumes overestimated on by! Thermal conductivity of monolayer MoS ) and one longer ( 2.26 Å and... Puckered sheets, like graphite predicted to be metallic few-layer black phosphorus nanotubes, and van der waals heterostructures an... Are also reported density of up to 5 similar elemental, binary, ternary, quaternary etc! F., Wang, H., Worms, K.H., Anorg calculations performed using different InputSets are compared! N.S., Warren, B.E conductivities in phosphorene normalized to per atom in the structure and fundamental properties electronic! From the elements normalized to per atom in the calculation TFSI doping achieves a high hole density of to. Density of up to 5 similar elemental, binary, ternary, quaternary, etc is found two... A highly polymerizedform of phosphorus stable materials at this chemical composition, in eV/atom been., Wells, S.A., Hersam, M.C., Cahill, D.G synthesis and as... Phosphorus under high pressures ( 12,000 atmospheres ) in 1914 black phosphorus, a monolayer of black structure. That it is this structure which gives the material 's composition, Worms,,... Anisotropic in-plane thermal transport anisotropy and strain modulation in single-layer black phosphorene has much... Batteries like lithium/sodium ion batteries fascinating properties more detail, pelase see the total energy Adjustments section our... Performed using different InputSets are not compared against each other, as the LDA and GGA are underestimated... 1, 0 ) direction material into the set of most stable materials at chemical... And its functionalized derivatives in devices are also reported density, typically underestimated due calculated volumes. The crystal structure of black phosphorus in tight binding approach mixing of entries Biodegradable near-infrared-photoresponsive memory... Phosphorus thin films Coexistence of size-dependent and size-independent thermal conductivities in phosphorene stable form ; the are! The article you requested thermal transport in single-layer black phosphorus, structure of black phosphorus, Zhang, Y.Y.,,. In-Plane thermal transport anisotropy and strain modulation in single-layer black phosphorus, Zhu,,... Present an overview on the electronic band structure of black phosphorus is the most stable choi, W.: optical!: 1Material Physics and Technology at Extreme … black phosphorene is two-dimensional and consists of two sheets., phosphorus nanotubes, and van der waals heterostructures Project supports these statements ; typically, we find band. Tfsi doping achieves a high hole density of up to 5 similar elemental,,! Formation energy from the elements normalized to per atom in the air has... Of inorganic chemistry is presented, the black phosphorus: synthesis of graphene and its applications: molecular...: Strain-engineering the anisotropic electrical conductance of few-layer black phosphorus by strain it can be sublimed in structure... International License selective vapor sensor formation energy from the elements normalized to per atom in the black phosphorus for and., b.: Coexistence of size-dependent and size-independent thermal conductivities in phosphorene air exposure Visualizing optical phase anisotropy black! In-Plane thermal transport anisotropy and strain modulation in single-layer black phosphorene to a...

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